publications list

For more details see

http://www.researcherid.com/rid/E-5925-2010

http://orcid.org/0000-0003-0650-3058

177
Affinity modulation of photoresponsive hosts for fullerenes: light-gated corannulene tweezers
Héctor Barbero, Sergio Ferrero, Lucia Alvarez-Miguel, Patricia Gómez-Iglesias, Daniel Miguel and Celedonio M. Álvarez,
Chem. Comm., 2016, 52, 12964-12967. DOI: 10.1039/c6cc06445k
176
Synergistic Effect of Tetraaryl Porphyrins Containing Corannulene and Other Polycyclic Aromatic Fragments as Hosts for Fullerenes. Impact of C60 in a Statistically Distributed Mixture of Atropisomers
Celedonio M. Álvarez, Héctor Barbero, Sergio Ferrero, and Daniel Miguel
J. Org. Chem., 2016, 81, 6081-6086. DOI: 10.1021/acs.joc.6b00454

175
Metallamacrocycle formation through dimerization of metal bioconjugates derived from amino acids and peptides
Celedonio M. Álvarez, Raúl García-Rodríguez and Daniel Miguel.
Dalton Trans., 2016, 45, 963-972. DOI: 10.1039/C5DT01256B

174
Multivalent Molecular Shuttles – Effect of Increasing the Number of Centers in Switchable Catalysts
Celedonio M. Álvarez, Héctor Barbero and Daniel Miguel.
Eur. J. Org. Chem., 2015, 6631-6640.

173
3-(Pyridin-2-yl)imidazo[1,5-a]pyridine (Pyridylindolizine) as Ligand in Complexes of Transition and Main-Group Metals
Celedonio M. Álvarez, Lucía Álvarez-Miguel, Raúl García-Rodríguez, José M. Martín-Álvarez and Daniel Miguel.
Eur. J. Inorg. Chem., 2015, 4921-4934. DOI: 10.1002/ejic.201500776

172
Luminescent rhenium(I) tricarbonyl complexeswith pyrazolylamidino ligands: photophysical,  electrochemical, and computational studies
Patricia Gómez Iglesias, Fabrice Guyon, Abderrahim Khatyr, Gilles Ulrich, Michael Knorr, José M. Martín Álvarez,  Daniel Miguel and Fernando Villafañe.
Dalton Trans., 2015, 44, 17516-17528.

171
Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexes
Patricia Gómez Iglesias, José M. Martín Álvarez,  Daniel Miguel and Fernando Villafañe.
Dalton Trans., 2015, 44, 17478-17481.

170
Assembling Nonplanar Polyaromatic Units by Click Chemistry. Study of Multicorannulene Systems as Host for Fullerenes
Celedonio M. Álvarez, Gabriel Aullón, Héctor Barbero, Luis A. García Escudero, Cristina Martínez-Pérez, José M. Martín Álvarez,  Daniel Miguel.
Org. Lett., 2015, 17, 2578-2581.

169
Enhanced association for C70 over C60 with a metal complex with corannulene derivate ligands.
Celedonio M. Álvarez, Luis A. García-Escudero, Raúl García-Rodríguez, José M. Martín Álvarez,  Daniel Miguel and Víctor M. Rayón.
Dalton Trans., 2014, 43, 15693-15696. DOI: 10.1039/C4DT02078B

168
Pyrazolylamidino Ligands from Coupling of Acetonitrile and Pyrazoles: A Systematic Study
Patricia Gómez Iglesias, Marta Arroyo,  Sonia Bajo, Carsten Strohman, Daniel Miguel, Fernando Villafañe.
Inorg. Chem., 2014, 53, 12437-12448.

167
Homo- and heteropolymetallic 3-(2-pyridyl)pyrazolate manganese and rhenium complexes.
Patricia Gómez Iglesias, Marta Arroyo, Noelia Antón, Raúl García Rodríguez, Elisabete C. B. Alegria, Armando J. L. Pombeiro, Daniel Miguel, Fernando Villafañe.
Dalton Trans., 2014, 43, 4009-4020.

166
Stereoselective Aldol Addition to Re(I) Complexes and  Reversible  Dimerization with Epimerization of the Metal Center
Celedonio M. Álvarez, Romen Carrillo,  Raúl García-Rodríguez, Daniel Miguel
Chem. Eur. J., 2013, 19, 8285-8293.

165
Schiff plus Click: One-pot Preparation of Triazole-Substituted Iminopyridines and Ring Opening of the Triazole Ring
Celedonio M. Álvarez, Luis A. García-Escudero,  Raúl García-Rodríguez and Daniel Miguel.
Dalton Trans., 2013, 42, 2556-2561. DOI: 10.1039/C2DT32400H.

164
η6-Hexahelicene Complexes of Iridium and Ruthenium: Running along the Helix.
Celedonio M. Álvarez, Héctor Barbero, Luis A. García Escudero, Jose M. Martín Álvarez, Cristina Martínez-Pérez,  Daniel Miguel
Inorg. Chem., 2012, 51, 8103-8111.

163
Intramolecular carboboration of carbonyl ligands to form boroxycarbenes.
Celedonio M. Álvarez, Romen Carrillo,  Raúl García-Rodríguez, Daniel Miguel
Chem Commun., 2012, 48, 7705-7707.

162
Triple Bridged Anionic Dimetallic Complexes from cis-[Mo(η3-methallyl)Cl(CO)2(NCMe)2] and Pyrazolates
Fernando  Lorenzo, Sonia Bajo, Daniel Miguel, Fernando  Villafañe
J. Organomet. Chem., 2012, 713, 68-71

161
Beyond Click Chemistry: Spontaneous C-triazolyl Transfer from Copper to Rhenium and Transformation into Mesoionic  C-triazolylidene Carbene
Celedonio M. Álvarez, Luis A. García-Escudero, Raúl García-Rodríguez, Daniel Miguel
Chem Commun., 2012, 48, 7209-7211.

160
Coordination vs. Coupling of Dicyanamide in Molybdenum and Manganese Pyrazole Complexes
Marta  Arroyo, Patricia  Gómez-Iglesias, José  M. Martín-Alvarez, Celedonio  M. Alvarez, Daniel  Miguel,  Fernando  Villafañe
Inorg. Chem., 2012, 51, 6070-6080.

159
Complexes with 3-(pyridyne-2-yl)imidazo[1,5-a]-pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction.
Celedonio M. Álvarez, Lucía Álvarez-Miguel, Raúl García-Rodríguez and Daniel Miguel.
Dalton Trans., 2012,41,7041-7046.

158
Molybdenum- and tungsten(II) monometallic 3-(2-pyridyl)pyrazole and bimetallic 3-(2-pyridyl)pyrazolate complexes.
Marta Arroyo, Daniel Miguel, Fernando Villafañe, Elisabete C. B. Alegria and Armando J. L. Pombeiro
Dalton Trans., 2012,41,7017-7025.

157
Macrocycle Formation by Proton-Template-Induced Dimerization of Complexes with (Alkoxoimino)pyridine.
Celedonio M. Álvarez, Raúl García-Rodríguez, José M. Martín-Álvarez, Daniel Miguel and José A. Turiel
Inorg. Chem., 2012, 51, 3938-3940.

156
Iminopyridine complexes of manganese, rhenium and molybdenum derived from amino ester methylserine, and peptides Gly-Gly, Gly-Val, and Gly-Gly-Gly Self-assembly of the peptide chain.
Celedonio M. Álvarez, Raúl García-Rodríguez and Daniel Miguel.
Inorg. Chem., 2012, 51, 2984-2986. DOI: 10.1021/ic2022984

155
pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes.
Celedonio M. Álvarez, Romen Carrillo, Raúl García-Rodríguez and Daniel Miguel
Chem Commun., 2011, 47, 12765-12767.

154
Tetranuclear organometallic complexes containing Mo2O42+ and allylmolybdenum(II) moieties.
Paloma Paredes, Angel Lopez-Calzada, Daniel Miguel and Fernando Villafañe
Dalton Trans., 2010, 39,10099-10104.

153
1,3,5-Tris(thiocyanatomethyl)mesitylene as a Ligand. Pseudooctahedral Molybdenum, Manganese, and Rhenium Carbonyl Complexes and Copper and Silver Dimers. Copper-Catalyzed Carbene- and Nitrene-Transfer Reactions.
Héctor Martinez-García, Dolores Morales, Julio Pérez, Marcos Puerto, and Daniel Miguel.
Inorg. Chem., 2010,49, 6974-6985.

152
Unexpected chemoselectivity in the Schiff condensation of amines with η2-(C,O)-η1(O)- coordinated aldehyde.
Celedonio M. Alvarez, Raul García-Rodríguez, Jose Manuel Martin Alvarez and Daniel Miguel
Dalton Trans., 2010, 39, 1201-1203.

151
Simple 1-dicyanomethylene-2-chloro-3-aminoindene push-pull chromophores: applications in cation and anion sensing.

Sara Basurto, Daniel Miguel, Daniel Moreno, Ana G. Neo, Roberto Quesada, Tomás Torroba.
Org. and Biomol. Chem., 2010, 8, 552-558.

150
fac-Acetato-bis(pyrazole) complexes: A systematic study on intra- and intermolecular hydrogen bonds.

Marta Arroyo, M. Teresa García-de-Prada, Carolina García Martín, Vanesa García-Pacios, Raúl García-Rodríguez, Patricia Gómez-Iglesias, Fernando Lorenzo, Isaac Martín Moreno, Daniel Miguel, Fernando Villafañe
J. Organomet. Chem., 2009, 694, 3190-3199.

149
Metal complexes with two different hydrogen-bond donor ligands as anion hosts.

Sonia Nieto, Julio Pérez, Lucía Riera, Víctor Riera, and Daniel Miguel
Chem. Commun., 2009, 3279-3281.

148
Non-covalent interactions at bis(pyrazole)silver(I) or -gold(I) cations.

Vanesa García-Pacios, Marta Arroyo, Noelia Antón, Daniel Miguel and Fernando Villafañe
Dalton Trans., 2009, 2135-2141.

147
Synthesis of new copper(I) complexes with tris(2-pyridyl) ligands. Applications to carbene and nitrene transfer reactions.

Julio Pérez, Dolores Morales, Luis A. García Escudero, Héctor Martínez García, Daniel Miguel and Pablo Bernad.
Dalton Trans., 2009, 375-382.

146
Manganese cationic pyrazolylamidino complexes.

Noelia Antón, Marta Arroyo, Patricia Gómez-Iglesias, Daniel Miguel, Fernando Villafañe.
J. Organomet. Chem., 2008, 693, 3074-3080.

145
A new route for the synthesis of an alkylideneamido complex.

Luciano Cuesta, Dolores Morales, Julio Pérez, and Daniel Miguel
New J. Chem., 2008, 32, 917-919.

144
Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters.

Javier A. Cabeza, Ignacio del Río, Daniel Miguel, Enrique Pérez-Carreño and M. Gabriela Sánchez-Vega
Dalton Trans., 2008, 1937-1942.

143
Second-sphere interaction of anions with a weakly binding metal complex host: probing the effect of counteranions.

Julio Pérez, Lucía Riera, Laura Ion, Víctor Riera, Kirsty M. Anderson, Jonathan W. Steed and Daniel Miguel
Dalton Trans., 2008, 878-886.

142
From an N-Methyl N-Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple C-H and C-N Bond Activation.

Javier A. Cabeza, Ignacio del Río, Daniel Miguel, M. Gabriela Sánchez-Vega
Angew. Chem. Int. Ed., 2008, 47, 1920-1922.

141
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects.

Javier A. Cabeza, Ignacio del Río, Daniel Miguel, Enrique-Pérez Carreño, M. Gabriela Sánchez-Vega
Organometallics, 2008, 27, 211-217.

140
Carbonyl complexes of manganese, rhenium and molybdenum with 2-pyridylimino acid ligands.

Celedonio M. Alvarez, Raúl García-Rodríguez, Daniel Miguel
J. Organomet. Chem., 2007, 692, 5717-5726.

139
Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N’-dipyrid-2-ylurea.

Javier A. Cabeza, Ignacio del Río, Lorena Martínez-Méndez, Daniel Miguel
J. Organomet. Chem., 2007, 692, 4407-4410.

138
Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity.

Javier A. Cabeza, Iván da Silva, Ignacio del Río, Robert A. Gossage, Lorena Martínez-Méndez, Daniel Miguel.
J. Organomet. Chem., 2007, 692, 4346-4352.

137
Pyridine-2-carboxaldehyde as ligand: Synthesis and derivatization of carbonyl complexes.

Celedonio M. Alvarez, Raul García-Rodríguez and Daniel Miguel
Dalton Trans., 2007, 3546-3554.

136
High-Nuclearity Osmium Carbonyl Cluster Complexes Containing (6-Methylpyrid-2-yl)imido Ligands. Synthesis of Hepta-, Octa-, and Nonanuclear Derivatives.

Javier A. Cabeza, Ignacio del Río, Pablo García-Alvarez, and Daniel Miguel
Organometallics, 2007, 26, 3212-3216.

135
A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru6(μ3-H)(μ5-k2-L)( μ-CO)(CO)15].

Javier A. Cabeza, Ignacio del Río,  Pablo García-Alvarez, Daniel Miguel
J. Organomet. Chem., 2007, 692, 3583-3587.

134
Pyrazole Complexes as Anion Receptors: Effects of Changing the Metal, the Pyrazole Substitution Pattern, and the Number of Pyrazole Ligands.

Sonia Nieto, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, James A. Golen, and Arnold L. Rheingold
Inorg. Chem., 2007, 46, 3407-3418.

133
Ruthenium Cluster Mediated Transformation of Linear Alkenes into Trienyl Ligands. Activation of Five C(sp3)-H Bonds of 1-Octene, 1-Nonene, and 1-Decene.

Javier A. Cabeza, Ignacio del Río, Pablo García Álvarez, and Daniel Miguel
Organometallics, 2007, 26, 2482-2484.

132
Biimidazole and Bis(amide)bipyridine Molybdenum Carbonyl Complexes as Anions Receptors.

Laura Ion, Dolores Morales, Sonia Nieto,  Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Richard A. Kowenicki, Mary McPartlin
Inorg. Chem., 2007, 46, 2846-2853.

131
Synthesis, Structure and Reactivity of Mononuclear Re(I) Oximato Complexes.

Luciano Cuesta, Miguel A. Huertos, Dolores Morales,  Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Amador Menéndez-Velázquez, Santiago García-Granda.
Inorg. Chem., 2007, 46, 2836-2845.

130
Reactivity of Indene, Fluorene, Azulene, and Acenaphthylene with a Basal-Edge-Bridged. Square-Pyramidal Hexaruthenium Dihydride.

Javier A. Cabeza, Ignacio del Río, Jose M. Fernandez-Colinas Pablo García-Álvarez, Daniel Miguel.
Organometallics, 2007, 26, 1414-1426.

129
Nonanuclear  Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton: Pentagonal Bipyramid with two Equatorial Edges Spanned by Metal Atoms

J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Organometallics, 2006, 25, 5672-5675.

128
Synthesis and Reactivity of New (Methoxymethyl Complexes of Manganese(I) and Rhenium(I).

E. Hevia, D. Miguel, J. Pérez, and V. Riera.
Organometallics, 2006, 25, 4909-4912.

127
Second-sphere coordination complex via hydrogen bonding: Synthesis, characterization, X-ray crystal structure determination and packing of  hexaamminecobalt(III) chloride di(para-dinitrobenzoate).

R. P. Sharma, R. Bala, R. Sharma, J. Pérez, and D. Miguel.
J. Mol. Struct., 2006, 797, 49-55.

126
Rhenium-Mediated Coupling of Acetonitrile and Pyrazoles. New Molecular Clefts for Anion Binding.

M. Arroyo, D. Miguel, F. Villafañe, S. Nieto, J. Pérez, and L. Riera
Inorg. Chem., 2006, 45, 7018-7026.

125
High-Nuclearity Ruthenium Carbonyl Cluster Complexes Derived from 2-Amino-6-methylpyridine: Synthesis of Nonanuclear Derivatives Containing µ4– and µ5-Oxo Ligands.

J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Inorg. Chem., 2006, 45, 6020-6027.

124
Second-sphere coordination complexes via hydrogen bonding: Synthesis, characterization of [Co(NH3)6](XO3)3.nH2O (X = Br, I) and single crystal X-ray structure determination of  [Co(NH3)6](BrO3)3.0.5H2O

R. P. Sharma, R. Bala, R. Sharma, J. Pérez, and D. Miguel.
J. Mol. Struct., 2006, 788, 49-54.

123
Carbonyl complexes of manganese, rhenium and molybdenum with ethynyliminopyridine ligands.

L. A. García-Escudero, D. Miguel and J. A. Turiel.
J. Organomet. Chem.,  2006, 691, 3434-3444.

122
Non-covalent interactions between anions and a cationic rheniun diamine complex: structural characterization of the supramolecular adducts.

S. Nieto, J. Pérez,  L. Riera, V. Riera,  and D. Miguel.
New J. Chem., 2006, 30, 838-841.

121
Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activity.

J. A. Cabeza, I. da Silva, I. del Río, R. A. Gossage, D. Miguel and M. Suarez.
Dalton Trans., 2006, 2450-2455.

120
Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride.

J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Organometallics, 2006, 25, 2683-2692.

119
Reactivity of Molybdenum and Rhenium Hydroxo Complexes toward Organic Electrophiles: Reactions that Afford Carboxylato Products

L. Cuesta, E. Hevia, D. Morales, J. Pérez, L. Riera and D. Miguel,
Organometallics, 2006, 25, 1717-1722.

118
Pyrazole Complexes as anion receptors

S. Nieto, J. Pérez, L. Riera, V. Riera and D. Miguel,
Chem. Eur. J., 2006, 12, 2244-2251.

117
Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6- methylpyridine. Novel coordination modes for 2-imidopyridines

J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel.
Can. J. Chem.,  2006, 84, 105-110.

116
Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond

J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, P. García-Álvarez and D. Miguel
Organometallics, 2006, 25, 1492-1499.

115
Molybdenum carbonyl complexes with pyridylimino acidato ligands

Raúl Garcia Rodriguez, Daniel Miguel
Dalton Trans., 2006, 1218-1225

114
Ruthenium cluster mediated activation of all bonds of methyl groups of 6,6’-dimethyl-2,2’-bipyridine and 2,9-dimethyl-1,10-phenantroline. Transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenantroline ligand

Javier A. Cabeza, Ignacio del Río, Lorena Martínez Méndez, Daniel Miguel
Chem. Eur. J.,  2006, 12, 1529-1538

113
From Cyclopentanone Oximes to Bis[1,2,3]dithiazolo-s-indacenes, Cyclopenta[c][1,2]thiazine, Pentathiepino-, Tetrathiino-, and Thienocyclopenta[1,2,3] dithiazoles as a Rich Source of New Materials.

Sonia Macho, Daniel Miguel, Teresa Gómez,TeresaRodríguez, TomasTorroba
J Org. Chem.,  2005, 70, 9314-9325

112
Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles

Teresa Gómez, Sonia Macho, Daniel Miguel, Ana G. Neo, Teresa Rodríguez, Tomás Torroba
Eur. J. Org. Chem., 2005, 5055-5066

111
Pyrazolylamidino and Bis(pyrazole)manganese(I) complexes.

Marta Arroyo, Alvaro López-Sanvicente, Daniel Miguel, Fernando Villafañe
Eur. J. Inorg. Chem., 2005, 4430-4437

110
Indene and pseudoazulene discotic liquid crystals: a synthetic and structural study.

Sara Basurto, Susana García, Ana G. Neo, Tomás Torroba, Carlos F. Marcos, Daniel Miguel, Joaquín Barberá, M. Blanca Ros, M. Rosario de la Fuente
Chem.Eur. J.,  2005, 11, 5362-5376

109
Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group.

Javier A. Cabeza, Ignacio del Rio, Daniel Miguel, M. Gabriela Sánchez-Vega
Chem. Commun., 2005,3956-3958

108
Activation of ancillary ligands in the reactions of DMAD with phosphido and alkylideneamido rhenium complexes

Luciano Cuesta, Eva Hevia, Dolores Morales, Julio Pérez; Víctor Riera; Markus Seitz, Daniel Miguel
Organometallics, 2005, 24, 1772-1775

107
New [Mo(h3-allyl)(CO)2L3]+ complexes with monodentate or tridentate nitrogen-donor ligands

Julio Pérez, Dolores Morales, Sonia Nieto, Lucía Riera, Víctor Riera, Daniel Miguel and Celedonio Alvarez
Dalton Trans., 2005, 884-888

106
Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives.

Javier A. Cabeza, Ignacio del Rio, Pablo García-Alvarez, Daniel Miguel.
Organometallics, 2005, 24, 665-674

105
Cationic fac-tris(pyrazole) complexes as anion receptors

Sonia Nieto, Julio Pérez, Víctor Riera, Daniel Miguel and Celedonio Alvarez
Chem.Comm., 2005, 546-548

104
Cyclopentathiadiazines, new heterocyclic materials from cyclic enaminonitriles

Sonia Macho, Daniel Miguel, Ana G. Neo, Teresa Rodríguez and Tomás Torroba
Chem.Comm., 2005, 334-336

103
Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex.

LucianoCuesta, Eva Hevia, Dolores Morales, Julio Pérez, Víctor Riera, Elena Rodríguez and Daniel Miguel
Chem.Comm., 2005, 116-117

102
Hexaruthenium Carbonyl Cluster Complexes with basal edge-bridged square pyramidal metallic skeleton: efficient synthesis of 2-iminopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions.

Javier A. Cabeza,  Ignacio del Río, Pablo García-Álvarez, Daniel Miguel, Víctor Riera
Inorg. Chem., 2004, 43, 5450-5458

101
Activation of all bonds of a methyl group attached to an organic fragment.

Javier A. Cabeza, Iván da Silva, Ignacio del Río, Lorena Martínez Méndez, Daniel Miguel, Víctor Riera
Angew. Chem. Int. Ed., 2004, 43, 3464-3467

100
Alkyl transfer reactivity in the first octahedral Isocyanide complex of nickel (II)

Enmanuel Boíllos, Daniel Miguel
Organometallics, 2004, 23, 2568-2572

99
Alkylation and metallation of binuclear anions caontaining a novel tricyclohexylphosphonioethanetrithiolate ligand  homodinuclear complex of manganese containing novel ligand, S(SR)C=C(PCy3)S}.

Yon Qiang Ma, Ning Yin,  Jing Li, Quing-lan Xie, Daniel Miguel
J. Organomet. Chem., 2004, 689, 1949-1955

98
A neutral organometallic fluoro complex can be a good ligand.

Laurent Coue, Luciano Cuesta, Dolores Morales, Jason A: Halfen, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Neil G. Connelly, Supakorn Boonyuen.
Chem. Eur. J., 2004, 10, 1906-1912

97
Reactivity of Molybdenum and Rhenium Hydroxo-Carbonyl Complexes toward Organic Electrophiles

Luciano Cuesta, Darío C. Gerbino, Eva Hevia, Dolores Morales, M. Elena Navarro-Clemente, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Igancio del Río, Santiago García-Granda
Chem. Eur. J., 2004, 10, 1765-1777

96
A homodinuclear complex of manganese containing novel ligand, Mn2(CO)6(m-H){ m-S(SC3H5)C=CPPri3)S}.

Yon Qiang Ma, Lei Yu, Cheng Song Hu, Xiao Chen, Jing Li, Hong Gen Wang, Daniel Miguel
J. Mol. Struct., 2003, 650, 45-48

95
Reactivity of [MCl(h3-allyl)(1,10-phenantroline)(CO)2] (M=Mo, W) Complexes Enolate Anions.

Dolores Morales, M. Elena Navarro-Clemente,  Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel
Organometallics, 2003, 22, 4124-4128

94
Molybdenum Amido Complexes with Single Mo-N Bonds: Synthesis, Structure, and Reactivity.

Dolores Morales, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Marta E. G. Mosquera, Santiago García-Granda
Chem. Eur. J., 2003, 9, 4132-4143

93
Building of dithiocarbamate and dithiocarbimate ligands within a heterobimetallic core

Jing Li, Daniel Miguel, Dolores Morales, Víctor Riera, Angel Aguirre-Pérez, Santiago García-Granda
Dalton Trans., 2003, 3264-3269

92
1,4-Thiazepines, 1,4-Benzothiazepin-5-ones, and 1,4-Benzothioxepin Orthoamides via Multicomponent Reactions.

Stefano Marcaccini, Daniel Miguel, Tomás Torroba, and María García-Valverde
J. Org. Chem., 2003, 68, 3315-3318

91
A new addition-rearrangement of [1,4]thiazine-2-thines with aryl-1,2,4-triazoline-3,5-diones

Nuria García, Pedro Fuertes, Susana Barriga, Ana G. Neo, Daniel Miguel, Tomás Torroba
Heterocycles, 2003, 60, 1083-1094

90
Synthesis of beta-lactams from a N-Rhenaimine: Effect of the Transition Metal on the Energetic Profile of the Staundinger Reaction

Julio Perez, Eva Hevia, Victor Riera, Daniel Miguel, Pablo Campomanes, M. Isabel Menendez, Tomas L. Sordo, Santiago Garcia-Granda
J. Am. Chem.Soc., 2003, 125, 3706-3707

89
Mono- and dimetallic Cyano Complexes with {Mo(h3-allyl)(CO)2(N-N)} fragments

Julio Perez, Eva Hevia, Lucía Riera, Victor Riera, Santiago García-Granda, Esther García-Rodríguez, Daniel Miguel
Eur. J. Inorg. Chem., 2003, 1113-1120

88
Synthesis of asymmetric heterotrimetallic gold clusters containing Mo, W, and Mn

Mei Wang, Daniel Miguel, Eva M. López, Julio Pérez, Víctor Riera, Claudette Bois, Yves Jeannin
Dalton Trans., 2003, 961-967

87
Synthesis of (h3-allyl)bromodicarbonyl bis(pyrazole)Molybdenum(II) and reactivity toward [Au(acac)PPh3]: Structure and dynamic behavior of the monometallic pyrazole and heterometallic pyrazolate complexes.

Paloma Paredes, Daniel Miguel, Fernando Villafañe
Eur. J. Inorg. Chem., 2003, 995-1004

86
The first pyrazole molybdenum(0) complexes: [Mo(CO)4(Hdmpz)2] crystallizes as a N-H…OC hydrogen-bonded dimer.

Paloma Paredes, Marta Arroyo, Daniel Miguel, Fernando Villafañe
J. Organomet. Chem., 2003, 667, 120-125

85
A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide.

D. C. Gerbino, E. Hevia, D. Morales, M. E. Navarro Clemente, J. Pérez, L. Riera, V. Riera, and D. Miguel.
J. Chem. Soc., Chem. Comm., 2003, 328-329.

84
Reactivity of the amido complex [Re(NHpTol)Ar)(CO)3(bipy)] toward neutral organic electrophiles.

E. Hevia, J. Pérez, V. Riera, and D. Miguel.
Organometallics, 2003, 21, 257-263.

83
Synthesis and structures of the first ruthenated benzodiazepines

J. Pérez, V. Riera, A. Rodríguez, and D. Miguel.
Organometallics, 2002, 21, 5437-5438

82
Manganese and Rhenium (I) Tricarbonyl (Alkylthio)methyl and Alkylidenesulfonium Complexes

E. Hevia, J. Pérez, V. Riera, and D. Miguel.
Organometallics, 2002, 21, 5312-5319

81
Synthesis of thiomorpholines by an intramolecular Ugi reaction

S. Marcaccini, R. Pepino, T. Torroba, D. Miguel, and M. García Valverde.
Tetrahedron Lett., 2002, 43, 8591-8593

80
Unexpected ortho-palladation of acetophenonephenylhydrazone

A. Carbayo, G. García Herbosa, S. García Granda, and D. Miguel
Inorg. Chim. Acta, 2002, 338, 260-264

79
The combination of organometallic {Mo(h3-allyl)(CO)2(phen)} fragments and hard aquo and hydroxo ligands: controlled synthesis and structural characterization

D. Morales, M. E. Navarro Clemente, J. Pérez, L. Riera, V. Riera, and D. Miguel.
Organometallics, 2002, 21, 4834-4838

78
Insertion and Cycloaddition Reactivity of the First Transition Metal N-Metallaimine

E. Hevia, J. Pérez, V. Riera, D. Miguel, S. García Granda, and I. del Río.
Angew. Chem. Int. Ed., 2002,41, 3858-3860

77
Insertion of unsaturated organic electrophiles into molybdenum-alkoxide and rhenium-alcoxide bonds of neutral, stable carbonyl complexes

E. Hevia, J. Pérez, V. Riera, D. Miguel, S. García Granda, and I. del Río.
Chem. Eur. J., 2002, 8, 4510-4521

76
Different site of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)3 (bipy)] (R= H or Me): N-H vs Re-N.

E. Hevia, J. Pérez, V. Riera, and D. Miguel.
J. Chem. Soc., Chem. Commun., 2002, 1814-1815

75
New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands.

E. Hevia, J. Pérez, V. Riera, D. Miguel, S. Kassel, and A. Rheingold.
Inorg. Chem., 2002, 41, 4673-4679

74
An analogue of cymantrene, [(h5C5H5)Mn(CO)3], containing a dimetalla dithiacyclo pentadienyl ring.

D. Miguel, D. Morales, V. Riera, and S. García Granda.
Angew. Chem. Int. Ed., 2002,41, 3034-3036

73
Formation of a 1-azaallenylidene ligand by reaction of an amido complex.

D. Morales, J. Pérez, L. Riera, V. Riera, and D. Miguel.
Inorg. Chem., 2002, 41, 4111-4113

72
Heterobinuclear complexes of Manganese and Molybdenum Containing Aminoacidato and Related O,N and S,N Bridges

B. Galán, D. Miguel, J. Pérez, and V. Riera
Organometallics, 2002, 21, 1979-2985

71
Reactivity of [MCl(h3-allyl)(CO)2(N-N)] complexes (M= Mo, W; N-N= bipy, phen) towards alkyl and acetylide anions

J. Pérez, L. Riera, V. Riera, S. García Granda, E. García Rodríguez, and D. Miguel.
Organometallics, 2002, 21, 1622-1626

70
The first structurally characterized acetanilido complex of palladium (II) and the maximum hardness principle. A sample of trans trans choice in square-planar complexes.

J. V. Cuevas, G. García Herbosa, D. Miguel, A. Muñoz.
Inorg. Chem. Commun., 2002, 5, 340-343

69
Reactive alkoxide complexes of groups 6 and 7 metals

E. Hevia, J. Pérez, L. Riera, V. Riera, and D. Miguel.
Organometallics, 2002, 21, 1750-1752

68
New octahedral Rhenium (I) tricarbonyl amido complexes

E. Hevia, J. Pérez, V. Riera, and D. Miguel.
Organometallics, 2002, 21, 1966-1974

67
An Easily Accessed Molybdenum Lewis Acid as Catalyst for Imine Aziridination

D. Morales, J. Pérez, L. Riera, V. Riera, S. García Granda, R. Corzo Suárez, and D. Miguel.
Organometallics, 2002, 21, 1540-1545

66
Molybdenum alkynyls as alkynyl transfer reagents

J. Pérez, L. Riera, V. Riera, S. García Granda, E. García Rodríguez, and D. Miguel.
J. Chem. Soc., Chem. Commun., 2002, 384-385

65
Synthesis and crystal structure of[(h3-C3H5)(CO)2Mo(m-S2CPCy3)-Mo(h3-CH2CMeCH2)(CO)2]

M. Wang, D. Miguel, V. Riera, C. Bois, and Y. Jeannin.
Trans. Met. Chem., 2001, 26, 566-569

64
Synthesis and Structure of an Asymmetric Binuclear Phenylhydrazonato Anionic Complex of Palladium Containing a Pd-C(aryl) Bond cis to a Pd-Amido Bond

A. Carbayo, J. V. Cuevas, G. García Herbosa, S. García Granda, and D. Miguel.
Eur. J. Inorg. Chem., 2001, 2361-2366

63
Synthesis of Thiadiazole, Dithietane, and Imine Derivatives of the [1,2]Dithiolo[1,4]thiazine Ring System

S. Barriga, P. Fuertes, C. F. Marcos, D. Miguel, O. A. Rakitin, C. W. Rees, and T. Torroba.
J. Org. Chem., 2001, 66, 5766-5771

62
Molybdenum and Tungsten Tricarbonyl Complexes with the Tripodal Ligands [nBuSn(2-pyridil)3] and [RSn(methylthiomethyl)3]

D. Morales, J. Pérez, L. Riera, V. Riera, and D. Miguel.
Organometallics, 2001, 20, 4517-4523

61
New Types of (Arene)ruthenium Alkynyl Complexes

C. Menéndez, D. Morales, J. Pérez, V. Riera, and D. Miguel.
Organometallics, 2001, 20, 2775-2781

60
Migrations of the Carbon Atom of the SC(H)PRLigand in the reducction/Protonation Processes of Heterodinuclear Mn-Re Complexes.

J. Li, D. Miguel, D. Morales, V. Riera, and S. García Granda.
Organometallics, 2001, 20, 3063-3069

59
The influence of nitrosyl and allyl ligands on the formation of metal-metal bonds in bimetallic complexes containing S2CPR3 ligands.

D. Miguel, V. Riera, and M. Wang
Inorg. Chim. Acta, 2000, 307, 20-25

58
Phosphine-carbon disulfide adducts, S2CPR3: versatile ligands in coordination chemistry (REVIEW)

A. Galindo, D. Miguel, J. Pérez
Coord. Chem. Rev., 1999, 193-195, 643-690

57
Reversible Isomerization via Migration of SnPh3 in S2CPR3-Bridged Heterobinuclear Compounds. X-Ray Structures of [(CO)3Re(µ-S2CPCy3)Mo(SnPh3)(CO)3] and [(CO)3(Ph3Sn)Re(µ-S2CPCy3)Mo(CO)3].

E. M. López, D. Miguel, J. Pérez, V. Riera, C. Bois, and Y. Jeannin.
Organometallics, 1999, 18, 490-494

56
Intramolecular Interactions Leading to Quasicubane Cages. Crystal Structures of [Mo2(NO)2(CO)4{µ-k2;k1-S2C(H)PCy3}2].

D. Miguel, V. Riera, M. Wang, C. Bois, S. Halut.
Inorg. Chem., 1998, 37, 5944-5947

55
Carbon-Sulfur Bond Cleavage of S2CPR3 Ligands in Dinuclear Complexes Promoted by Reduction and Protonation.

J. Li, D. Miguel, M. D. Morales, V. Riera, and S. García Granda.
Organometallics, 1998, 17, 3449-3453

54
Coupling of h3-allyl and Alkyne in Molybdenum Carbonyl Complexes.

G. Barrado, M. M. Hricko, D. Miguel, V. Riera, H. Wally, and S. García Granda.
Organometallics, 1998, 17, 820-826

53
Synthesis and Structure of a Tetrametallic Acetylene

D. Miguel, M. Moreno Cuartas, J. A. Pérez, V. Riera, D. G. Churchill, M. R. Churchill, and T. S. Janik
J. Am.  Chem. Soc., 1998, 120, 417-418

52
Preparation and Reactivity of Mono- and Binuclear Nitrosyl Molybdenum Complexes Containing S2CPCy3 Ligands. Crystal Structure of [(CO)2(NO)Mo(µ-Br)(µ-S2CPCy3)Mo(CO)2(PEt3)].

D. Miguel, V. Riera, M. Wang, C. Bois, Y. Jeannin.
J. Organomet. Chem., 1997, 545-546, 327-336

51
Dirhenium Complexes with S2CPR3 Donating Four and Eight Electrons. X-Ray Structures of [Re2(CO)8(µ-S2CPCy3)] and [Re2(CO)6(µ-S2CPCy3)].

B. Alvarez, J. Li, D. Miguel, M. D. Morales, V. Riera, S. García Granda.
Chem. Ber., 1997, 130, 1507-1511

50
Diastereospecific Dimerization in Bridging Amido Complexes of Dipalladium

J. V. Cuevas, G. García Herbosa, A. Muñoz, S. García Granda, and D. Miguel.
Organometallics, 1997, 16, 2220-2222

49
Hydride Addition to Coordinated S2CPR3 Ligands in Mononuclear Mn and Re Complexes: Phosphine-Dithioformate Adducts as Five-Electron Bridging Ligands. X-Ray Structure of [Mn2(CO)6{µ-S2C(H)PCy3}2].

G. Barrado, D. Miguel, J. A. Miguel, V. Riera, X. Soláns.
Chem. Ber., 1996, 129, 1535-1540.

48
Synthesis, Structure and Reactivity of the Complexes Fe(h3-S2CPR3)(CO)3. The Electronic Factors Affecting the Dichotomy between h2 and h3 Coordination Modes in Transition Metal Complexes of Dithiocarboxy Ligands.

A. Galindo, C. Mealli, J. Cuyás, D. Miguel, J. A. Pérez Martínez, V. Riera, C. Bois, Y. Jeannin.
Organometallics, 1996, 15, 2735-2744

47
Palladium complexes with the Tridentate Dianionic Ligand Pyridine-2,6-dicarboxylate, dipic. Crystal Structure of [Pd(dipic)(PBu3)]2

P. Espinet, J. A. Miguel, S. García Granda, and D. Miguel.
Inorg.Chem., 1996, 35, 2287-2291

46
The Reduction and Oxidation of Cationic Carbonyl Complexes with Phosphoniodithioformate Ligands. X-Ray Crystal Structure of [Mn(CO)4(S2CPCy3)]ClO4]

G. A Carriedo, D. Miguel, J. A. Pérez Martínez, V. Riera, S. García Granda, and E. Pérez Carreño.
J. Organomet. Chem., 1996, 511, 77-84

45
Curso de Introducción a la Química Organometálica (Textbook)

G. A Carriedo, D. Miguel
Servicio de Publicaciones de la Universidad de Oviedo

44
Reduction Reactions of Binuclear Manganese-Molybdenum Complexes containing S2CPR3and Bidentate P-Donor Bridges. X-Ray Structure of [MnMo(SnPh3)(CO)4(µ-tedip)(µ-S2CPCy3)]

E. M. López, D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
J. Organomet. Chem., 1995, 492, 23-29

43
h3-Allyl Molybdenum Dithiophosphate and Dithiophosphinate Complexes with Mono and Bidentate Nitrogen Donor Ligands. X-Ray Structure of [Mo2(h3-C3H5)2(CO)4{S2P(OEt)2}(µ-NH2NH2)]

G. Barrado, D. Miguel, V. Riera, and S. García Granda.
J. Organomet. Chem., 1995, 489, 129-135

42
Domination of electronic factors in the selective metal to carbon bond formation in binuclear manganese-molybdenum complexes with S2CPRbridges

D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
Organometallics, 1994, 13, 4667-4669

41
Heterodinuclear complexes containing S2CPRas asymmetric bridges between cobalt and metals of group 7 (Mn, Re) or group 6 (Mo,W): Selective cobalt-carbon bond formation.X-Ray structures of [MnCo(CO)5(µ-S2CPCy3)] and [MoCo(h3-C3H5)(CO)4(µ-S2CPCy3)].CH2Cl2.

G. Barrado, J. Li, D. Miguel, J. A. Pérez Martínez, V. Riera, C. Bois, and Y. Jeannin.
Organometallics, 1994, 13, 2330-2336

40
Cyclopalladated complexes of 2-Acetylpyridine Phenylhydrazone: A terdentate C,N,N’ Donor Ligand.

G. García Herbosa, A. Muñoz, D. Miguel, and S. García Granda.
Organometallics, 1994, 13, 1775-1780

39
Homo- and Heterobimetallic, Mixed Valence MII/MComplexes of Molybdenum and Tungnsten with S2CPR3Ligands. X-Ray structure of [(h3-C3H5)(CO)2Mo(µ-Br)(µ-S2CPCy3)Mo(CO)3].

D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
Organometallics, 1994, 13, 1336-1340

38
Desulfurization and C-C coupling in the reaction of the anions [MnM(CO)6(µ-H)(µ-S2CPCy3)] (M= Mn, Re) with carbon disulfide. X-Ray structure of [Li(THF)3] [[MnM(CO)6(µ-H){µ-S(S)C=C(PCy3)S}] and [Mn2(CO)6(µ-H)(µ-ClCH2SC(S)P(cyclo-C6H11)3].

B. Alvarez, S. García Granda, J. Li, D. Miguel, and V. Riera.
Organometallics, 1994, 13, 16-17

37
Arene Ruthenium Complexes with S2CPR3 and Trichlorostannato Ligands.

B. Alvarez, D. Miguel, J. A. Pérez Martínez, andV. Riera.
J. Organomet. Chem., 1994, 474, 143-147

36
Heterodinuclear Complexes of Rhenium and Molybdenum with Bridging S2CPR3 Ligands

E. M. López, D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
J. Organomet. Chem., 1994, 467, 231-235

35
Seven-coordinate molybdenum-tin complexes containing phosphorodithioato and phosphoniodithioformate. X-Ray Structure of [Mo(CO)2{S2P(OEt)2}(S2CPCy3)(SnPhCl2)].CH2Cl2

G. Barrado, D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
J. Organomet. Chem., 1994, 466,147-151

34
Metal-Metal Bond Formation and Rearrangement of the S2CPR3 Ligands in Binuclear Manganese-Molybdenum Complexes. X-Ray Structure of [MnMo(SnPh3)(CO)6(µ-S2CPPri3)]..

D. Miguel, J.A. Pérez Martínez, V. Riera, and S. García Granda.
Organometallics, 1993,12, 2888-2890

33
Acetylacetonato as bridging k(O),k(O’) Ligand.X-Ray Structure of [{Mn(CO)3(dppe)}2{µ-acac)]ClO4.

B.Alvarez, C. Bois, Y.Jeannin, D. Miguel, and V. Riera.
Inorg. Chem., 1993, 32, 3783-3785

32
Seven-coordinate molybdenum complexes containing SnRCl2and phosphorodithioate . X-Ray Structure of [Mo(CO)2{P(OMe)3}2{S2P(OEt)2}(SnBuCl2)].

G. Barrado, D. Miguel, J.A. Pérez Martínez, V. Riera, and S. García Granda.
J. Organomet. Chem., 1993, 463, 127-133

31
S2CPR3 adducts as Bi-nucleating Ligands. Novel Heterobimetallic Complexes with S2CPR3 Bridges of Eight and Six Electrons. X-Ray Structure of [MnMo(CO)6(µ-Br)(µ-S2CPPri3)] and [MnMo(CO)5(µ-Br)(µ-S2CPCy3)(µ-tedip)]

D. Miguel, J.A. Pérez Martínez, V. Riera, and S. García Granda.
Organometallics, 1993, 12, 1394-1400

30
Seven-coordinate molybdenum-tin and tungsten-tin complexes containing phosphites and tetramethylthiourea:. X-Ray Structure of [Mo(CO)2{P(OMe)3}3(SnBuCl2)Cl].

D. Miguel, J.A. Pérez Martínez, V. Riera, and S. García Granda.
J. Organomet. Chem., 1992, 445, 121-127

29
The first cationic heterobinuclear complexes with bridging S2CPR3 ligands. X-Ray Structure of [(h6-C6Me6)Ru(µ-Cl)(µ- S2CPCy3)W(CO)3)]PF6.CH2Cl2.

J. Cuyás, D. Miguel, J.A. Pérez Martínez, V. Riera, and S. García Granda.
Polyhedron, 1992, 11, 2713-2716.

28
S2CPR3 Adducts as Bridging ligands in tricobalt clusters. X-Ray Structure of [Co3(CO)7(SnCl3)(µ3-CH)(µ2-S2CPCy3)]

B. Alvarez, D. Miguel, V. Riera, and S. García Granda.
J. Organomet. Chem., 1992, 430, C19-C22

27
The first examples of insertion of SnCl2into the Mn-Cl an Re-Cl bonds of octahedral complexes. X-Ray Structure of [Mn(CO)3(SnCl3)(S2CPCy3)].CH2Cl2

B. Alvarez, D. Miguel,J. A. Pérez Martínez, V. Riera, and S. García Granda.
J. Organomet. Chem., 1992, 427, C33-C36

26
Stable Intermediates in the Oxidative Addition/Reductive Elimination of Sn-Cl Bonds to Molybdenum Compounds. X-Ray Crystal Structure of [Mo(CO)2(PCy3)(µ-Cl)(µ-S2CPCy3) (SnBuCl2)] .CH2Cl2

D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
Angew. Chem. Int. Ed. Engl., 1992,31, 76-77

25
S2CPR3 as Bi-Nucleating Ligands. Novel Heterobimetallic Complexes with h2(S,S’), h3(S,C,S’) S2CPR3 bridges of 8e. X-Ray Structure of [MnMo(CO)6(µ-Br)(µ-S2CPPri3)]

D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
J. Organomet. Chem., 1992, 420, C12-C15

24
Reactivity of 8e S2CPR3 Bridges with Nucleophiles: Formation of Phosphoniodithioformate Esters as novel Bridging Ligands of 7 e. X-Ray Crystal Structures of NEt4[Mn2(CO)6(µ-S2CH)] and [Mn2(CO)6(µ-H)(µ-ClCH2SC(S)P(cyclo-C6H11)3]

B. Alvarez, S. García Granda, Y. Jeannin, D. Miguel, J. A. Miguel, and V. Riera.
Organometallics, 1991, 10, 3005-3007

23
Substituted seven-coordinate molybdenum-tin and tungsten-tin complexes from M(CO)6, BuSnCl3, and phosphites. X-ray structure of [Mo(CO)2{P(OMe)3}3(SnBuCl2)Cl]

D. Miguel, J. A. Pérez Martínez, V. Riera, and S. García Granda.
Polyhedron, 1991, 10, 1717-1720

22
Ring opening and closing in (CO)n(L)MnIcomplexes where L= S2CPCy3 or diphosphine. Novel complexescontaining the Mn(µ-L)AuC6F5 entity whereL= S2CPCy3 or dppm.

D. Miguel, V. Riera, and J. A. Miguel.
J. Organomet. Chem., 1991, 412, 127-136

21
Trialkylphosphine-Carbon Disulfide Adducts as Eight Electron Bridging Ligands. X-Ray Structures of [Mn2(CO)6(µ-S2CPCy3)] and [Mn2(CO)4(µ-dppm)(µ-S2CPCy3)

D. Miguel, V. Riera, J. A. Miguel, M. Gómez, and X. Soláns.
Organometallics, 1991, 10, 1683-1692

20
Selective Metal to Carbon Bond Formation in the Synthesis of the First Rhenium Complexes with S2CPCy3 ligands. X-Ray Crystal Structures of [MnRe(CO)6(µ-S2CPCy3)] and [Re2(CO)8(µ-S2CPCy3)] ]

B. Alvarez, D. Miguel, V. Riera, J. A. Miguel, and S. García Granda.
Organometallics, 1991, 10, 384-387

19
Improved Synthesis, Solution and Solid State Structure, and Reactivity of [Ru2(µ-SePh)2(CO)6]

P. L. Andreu, J. A. Cabeza, D. Miguel, V. Riera, M. A. Villa, and S. García Granda.
J. Chem.Soc., Dalton Trans., 1991, 533-536

18
Octahedral Alkylidyne Complexes of Tungsten with Chelating Ligands as Precursors for Polynuclear Compounds. Crystal Structures of [W(CR)(CO)2(dmpe)(NCS)] and [Co2W(µ3-CR)(CO)8 (dmpe)(Br)

G. A. Carriedo, G. Sánchez, V. Riera, C. Bois, Y. Jeannin, and D. Miguel.
J. Chem.Soc., Dalton Trans., 1990, 3355-3362

17
Manganese Complexes with S2CPEt3 ligands. X-Ray Crystal Structures of cis-trans-[Mn(CO)2(PEt3)2(S2CPEt3)]ClO4 and cis-trans-[Mn(CO)2 (PEt3)2 (S2CH)].]

D. Miguel, V. Riera, J. A. Miguel, F. Diego, C. Bois, and Y. Jeannin.
J. Chem.Soc., Dalton Trans., 1990, 2719-2727

16
The Different Reactivity of 2-Aminopyridines and 2-Pyridone with [Ru3(CO)12]. X-Ray Crystal Structure of [Ru3(µ-H)(µ3-anpy)(CO)9](Hanpy = 2-Anilinopyridine]

P. L. Andreu, J. A. Cabeza, V. Riera, Y. Jeannin, and D. Miguel
J. Chem.Soc., Dalton Trans., 1990, 2201-2206

15
The thermal and photochemical reactions of [Ru3(CO)12] with tetraethyl- diphosphite. X-Ray Structure of [Ru3(CO)10{µ-(EtO)2POP(OEt)2}] ]

J. A. Cabeza, V. Riera, Y. Jeannin, and D. Miguel
Inorg. Chim. Acta, 1990, 168, 77-82

14
Ruthenium-Platinum Carbonyl Cluster Complexes with Bridging Methylene, Methylidyne, and Carbido Ligands; Crystal Structures of the Compounds [Ru2Pt(µ-CH2)(µ-CO)(CO)2{P(cyclo-C6H11)3}(h-C5H5)2], [Ru2Pt2(µ-H)(µ4-CH)(µ-CO)(CO)2(PPri3)(h-C5H5)2], and[Ru2Pt2(µ-H)(µ4-C)(µ-CO)2(PPri3)2 (h-C5H5)2]

D. L. Davies, J. C. Reffery, D. Miguel, P. Sherwood, and F. G. A. Stone.
J. Organomet. Chem., 1990, 383, 463-480

13
A Phosphane -Dithioformate Adduct as a Five-Electron Bridging Ligand. [Mn2(CO)6{S2C(H)P(cyclo-C6H11)3}2]

D. Miguel, J. A. Miguel, V. Riera, and X. Soláns.
Angew. Chem., Int. Ed. Engl., 1989, 28, 1014-1016

12
Synthesis of the Compounds [Re(=CR)(CO)2(h5-C9H7)][BF4] (R= C6H4Me-4 or C6H3Me2-2,6) and the Preparation of complexes with Fe-Re Bonds

D. Miguel, U. Steffan, and F. G. A. Stone.
Polyhedron, 1988, 7, 443-448

11
s-Alkynyl Complexes of Manganese asLigands. Preparation, Crystal Structure and Reactivity of {[Co2(CO)6] [µ-PhCCMn(CO)4(PCy3)]} (Cy=cyclohexyl)

G. A. Carriedo, D. Miguel, and V. Riera.
J. Organomet. Chem., 1988, 342, 373-380

10
Transformations of µ-Methylene-diruthenium Complexes into Tetranuclear Metal Clusters with µ4-Methylene and µ4-Carbido Groups: X-Ray Crystal Structures of [Ru2Pt2(µ-H)(µ4-CH)(µ-CO)(CO)2(PiPr3)2(h-C5H5)2] and [Ru2Pt2(µ-H)(µ4-C)(µ-CO)2(PiPr3)2(h-C5H5)2]

D. L. Davies, J. C. Reffery, D. Miguel, P. Sherwood, and F. G. A. Stone.
J. Chem.Soc., Chem. Comm.. 1987, 454-456

9
Manganese(I) Complexes with (Tricyclohexylphosphonio)dithiocarboxilate as Chelate and Unidentate Ligand. X-Ray Crystal Structure of fac-[Mn(CO)3 {S2CP(C6H11)3}2]ClO4.H2O

D. Miguel, V. Riera, J. A. Miguel, C. Bois, M. Philoche Levisalles, and Y. Jeannin.
J. Chem.Soc., Dalton Trans., 1987, 2875-2880

8
New Bonding Mode of Tricyclohexylphosphoniodithiocarboxylate (S2CPCy3) as an Eight-Electron Donor. Synthesis, Reactivity, and X-Ray Structure of [Mn2(CO)6(S2CPCy3)]

D. Miguel, V. Riera, J. A. Miguel, X. Soláns, and M. Font-Altaba.
J. Chem.Soc., Chem. Comm., 1987, 472-474

7
s-Alkynyl Complexes of Manganese(I) as h2-Bonding Ligands for Group 1B Metal-Ligand Fragments. X-Ray Structure of [Mn2Cu (µ-CCBut)2 (CO)6(dppe)2]PF6.0.5CH2Cl2

G. A. Carriedo, D. Miguel, V. Riera, and X. Soláns.
J. Chem.Soc., Dalton Trans., 1987, 2867-2873

6
Structure of fac-Tricarbonyl(tert-butylethynyl)[ethylenebis(diphenylphosphine)] manganese(I)

M. L. Valín, D. Moreiras, X. Soláns, D. Miguel, and V. Riera.
Acta Cryst. Sect. C, 1986, C42, 977-979

5
Structure of a Copper Chloride Adduct of a Manganese (I) Complex

X. Soláns, J. Soláns, C. Miravitlles, D. Miguel, V. Riera, and J. M. Rubio González.
Acta Cryst. Sect. C., 1986, C42, 975-977

4
s-Alkynyl Complexes of Manganese(I) as Ligands. Synthesis and X-Ray Structure of {[h2-ButC2Mn(CO)3(dppe)]2Cu}(PF6)]

G. A. Carriedo, D. Miguel, V. Riera, X. Soláns, M. Font-Altaba, and M. Coll.
J. Organomet. Chem., 1986, 299, C43-C46

3
Synthesis of Manganese(I) Carbonyls with s-bonded Alkynyl Ligands]

D. Miguel, and V. Riera.
J. Organomet. Chem., 1985, 293, 370-390

2
Manganese(I) Carbonyls withs-bonded Alkynyl Ligands. The Crystal Structure of [Co2(CO)6] [PhCCMn(CO)4{P(C6H11)3}]

G. A. Carriedo, V. Riera,D. Miguel, A. M. Manotti Lanfredi, and A. Tiripicchio.
J. Organomet. Chem., 1984, 272, C17-C20

1
Synthesis of Cationic Carbonyl Complexes of Manganese(I) with Bidentate Ligands.

M. P. Gamasa, M. Laguna, D. Miguel, and V. Riera.
Trans. Met. Chem., 1981, 6, 374-376